Open AccessThe OPAHs from hemicellulose pyrolysis tar at different temperature characterization via GC-MS and ESI FT-ICR MS
Author(s) -
Lingfeng Xiao,
Song Hu,
Long Jiang,
Song Hu,
Yi Wang,
Jun Xiang
Publication year - 2021
Publication title -
iop conference series. earth and environmental science
Language(s) - English
Resource type - Journals
eISSN - 1755-1307
pISSN - 1755-1315
DOI - 10.1088/1755-1315/657/1/012028
Subject(s) - hemicellulose , tar (computing) , chemistry , pyrolysis , furfural , gas chromatography–mass spectrometry , organic chemistry , mass spectrometry , chromatography , lignin , catalysis , computer science , programming language
The OPAHs from hemicellulose tar are high risk of causing cancer during thermal conversion. Therefore, the distribution of OPAHs in hemicellulose tar at different temperatures characterization via GC-MS and ESI FT-ICR MS. It is found that pyrolysis tar of xylan contain a large amount of furfural and L-glucan by GC-MS. While the ESI FT-ICR MS shows that The molecular mass of OPAHs in the tar mainly concentrate between 200 Da and 400 Da and these compounds are mostly with C atoms from 5 to 25 and DBE values from 4 to 15. Moreover, there are more decarbonylation and decarboxylation reactions with the pyrolysis temperature raise.