Open AccessSynthesis and Crystal Structure of N, N’-Bisphenylacetic Hydrazide
Author(s) -
Lihua Wang,
Ke Xu,
Ning Wang
Publication year - 2020
Publication title -
iop conference series. earth and environmental science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.179
H-Index - 26
eISSN - 1755-1307
pISSN - 1755-1315
DOI - 10.1088/1755-1315/440/2/022055
Subject(s) - triclinic crystal system , hydrazide , hydrogen bond , crystal structure , molecule , crystallography , intermolecular force , crystal (programming language) , chemistry , stereochemistry , materials science , organic chemistry , computer science , programming language
A bishydrazone compound, C 16 H 16 N 2 O 2 , has been synthesized by the reaction of phenylacetic hydrazide and phenylacetyl chloride in CH 3 CH 2 OH solution. The crystal structure of C 16 H 16 N 2 O 2 has been characterized by single crystal X-ray diffraction analysis. The result shows that the N, N’ -Bisphenylacetic hydrazide belongs to triclinic, space group P -1 with a = 5.5280(11) Å, b = 8.0010(16) Å, c = 15.279(3) Å, a = 94.39(3)°, β = 92.20(3)°, γ = 91.52(3)°, V = 673.0(2)Å 3 , Z = 2, Dc = 1.324 mg·m −3 , μ = 0.089 mm −1 , F (000) = 284, and final R 1 = 0.0447, ωR 2 = 0.1041. The N, N’- Bisphenylacetic hydrazide molecules form 1D chained structure by the intermolecular hydrogen bonding interactions along the bc plane.