Open AccessSyntheses of Biodegradable Polylactides Catalyzed by Aluminum Complexes bearing Phenanthrene Derivatives for Polymerization of Lactides
Author(s) -
Dongni Li,
Bo Gao,
Yanhui Li,
Qian Duan
Publication year - 2019
Publication title -
iop conference series. earth and environmental science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.179
H-Index - 26
eISSN - 1755-1307
pISSN - 1755-1315
DOI - 10.1088/1755-1315/330/4/042015
Subject(s) - polymerization , phenanthrene , chemistry , catalysis , isopropyl alcohol , isopropyl , polymer chemistry , bearing (navigation) , organic chemistry , polymer , cartography , geography
A methylaluminum Schiff base compound 1 bearing phenanthrene derivatives was made and used in the ROP of LA. Compound 1 was characterized by NMR and elemental analysis. Compound 1 with isopropyl alcohol exhibited good activity towards the polymerization experiment of LA. The ROP is in a coordination-insertion mechanism.