Open AccessImproving the triple-cation perovskite solar cells by two-step deposition methods with perovskite seeds
Author(s) -
P Phiromruk,
S. Chatraphorn
Publication year - 2021
Publication title -
journal of physics. conference series
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.21
H-Index - 85
eISSN - 1742-6596
pISSN - 1742-6588
DOI - 10.1088/1742-6596/2145/1/012028
Subject(s) - chlorobenzene , perovskite (structure) , halide , deposition (geology) , perovskite solar cell , materials science , layer (electronics) , spin coating , chemical engineering , substrate (aquarium) , coating , inorganic chemistry , chemistry , nanotechnology , organic chemistry , catalysis , paleontology , oceanography , sediment , geology , engineering , biology
As of recent years, triple-cation perovskite solar cells have received immense attention due to its superior efficiency and better stability comparing to the classic single-cation perovskite solar cells such as MAPbI 3 or FAPbI 3 . A triple-cation perovskite layer which has been used most recently is cesium-containing FAPbI 3 -based perovskite. One of decent approaches to fabricate the layer is spin-coating technique by using two-step deposition process in which mixed lead-halide and CsI precursor is firstly spin-coated onto a substrate, then organic cation solution is deposited on the lead-halide layer. In this work, the results show that the performance of the devices from this process is lower than expected that could be due to difficulty of cesium ion incorporation as a stabilizer for FAPbI 3 -based perovskite. Perovskite seeding growth is introduced to solve the problem where the process is slightly modified from conventional two-step deposition methods by adding small amount of perovskite seed precursor into PbI 2 solution. The concentration of the perovskite seed in PbI 2 solution was varied for 0, 7, 14 and 20% v/v. The highest average efficiency of 11.9% was obtained from 7% v/v seeding concentration. Furthermore, the device performance could be improved by using proper amount of chlorobenzene (CB) as an anti-solvent. The highest efficiency of 18.4% was achieved by using 30 µl of chlorobenzene.