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Physical-and-chemical calculations of safe mode of propane transportation
Author(s) -
A A Katansky,
N G Zhuravleva,
M E Pankratova,
M A Pastushkova,
A A Trotsenko
Publication year - 2021
Publication title -
journal of physics. conference series
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.21
H-Index - 85
eISSN - 1742-6596
pISSN - 1742-6588
DOI - 10.1088/1742-6596/2094/5/052056
Subject(s) - flammable liquid , propane , explosive material , ignition system , flash point , nuclear engineering , flammability limit , environmental science , minimum ignition energy , materials science , thermodynamics , chemistry , forensic engineering , waste management , mechanics , engineering , physics , organic chemistry
The key criteria used to assess fire-and-explosive hazard of any facility are: flash point, self-ignition temperature and minimum ignition energy. This article addresses how fire-and-explosive hazard criteria can be used to forecast emergency situations while transporting great quantities of flammable substance – propane, based upon ambient environment temperature. Calculations that were made have led to a conclusion that fire-and-explosive safety concentration mode for propane handling will be: lower concentration value is equal to 1.27 % or under than that value; upper concentration value is equal to 13.96 % or greater than that value. When selecting safe transportation and storage conditions for self-igniting combustible substances, great attention is given to relationship between environment, mass of substance transported and time-period to spontaneous ignition. For propane, the safe self-ignition temperature is deemed to be less than 360°C. Calculations for theoretical experiment regarding propane transportation were made based upon three critical temperature values: 1) 25 °C+10 °C - initial starting point when ambient temperature is 25 °C (roadway temperature is disregarded because ambient temperature is not high enough); 2) 60 °C+10 °C – point of arrival where ambient temperature is 60 °C; 3) 470 °C – propane self-ignition temperature. This helped us to figure out that propane can be stored and transported safely if the minimal electric ignition source is under 4 *10 −6 Joule .

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