Open AccessNumerical calculation of intermolecular bonds under the action of ultrasonic cavitation
Author(s) -
Roman N. Golykh,
Vladimir N. Khmelev,
Ivan A Manyakhin,
Д.А. Ильченко,
Vyacheslav D. Minakov,
Vladislav A. Shakura
Publication year - 2021
Publication title -
journal of physics. conference series
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.21
H-Index - 85
eISSN - 1742-6596
pISSN - 1742-6588
DOI - 10.1088/1742-6596/2094/2/022074
Subject(s) - cavitation , viscosity , breakup , ultrasonic sensor , polymer , macromolecule , materials science , intermolecular force , reduced viscosity , action (physics) , thermodynamics , volume viscosity , chemistry , composite material , mechanics , acoustics , organic chemistry , physics , molecule , biochemistry , quantum mechanics
The linear model of macromolecules was proposed. Expression for probability of macromolecules breakup under ultrasonic cavitation action was obtained. The fractional composition and viscosity of uncured polymer were calculated. As a result of the calculations, it was evaluated that the cavitation-acoustic effect for a time of no more than 1 min at an vibration intensity of at least 6 W/cm 2 and an initial viscosity of 0.2 Pa· s reduces the viscosity of polymers by at least 8 times. At the same time, it was theoretically revealed that the cavitation-acoustic effect is also capable of reducing the viscosity of polymers with an initial viscosity of more than 1 Pa·s up to 4 times.