
ZIF-67-aerogel-derived N-doped carbon nanotubes encapsulated with Co nanoparticles as efficient electrocatalysts
Author(s) -
Yan Li,
Hengguo Wang
Publication year - 2021
Publication title -
journal of physics. conference series
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.21
H-Index - 85
eISSN - 1742-6596
pISSN - 1742-6588
DOI - 10.1088/1742-6596/2085/1/012030
Subject(s) - aerogel , carbon nanotube , materials science , electrocatalyst , nanotechnology , nanoparticle , catalysis , cobalt , electrochemistry , chemical engineering , electrode , chemistry , organic chemistry , metallurgy , engineering
Electrocatalyst for oxygen reduction reaction (ORR) are essential for metal-air batteries. Herein, we design a self-catalyzed growth strategy for in-situ encapsulation of Co nanoparticles with N-doped carbon nanotubes (NCNT) on carbon aerogel (CA) (Co/NCNT/CA-1000). Using the zeolite imidazole framework (ZIF-67) as the cobalt source can catalyze the graphitization of melamine and facilitate the growth of NCNTs on the CA. Thanks to its unique structure, the Co/NCNT/CA-1000 exhibits favourable ORR properties (E 1/2 = 0.80 V). This work offers an effective method for preparing high-active Co-based electrocatalysts and provides a foundation for the future development of electrochemical energy applications.