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X-ray spectral analysis of surface structures formed on copper alloys during film fasting
Author(s) -
Вадим Іванович Кубіч,
O G Cherneta,
V.М. Yurov,
V.P. Oleshko
Publication year - 2021
Publication title -
journal of physics. conference series
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.21
H-Index - 85
eISSN - 1742-6596
pISSN - 1742-6588
DOI - 10.1088/1742-6596/1901/1/012091
Subject(s) - redistribution (election) , surface tension , grease , lubricant , copper , materials science , non equilibrium thermodynamics , metallurgy , thermodynamics , composite material , law , physics , politics , political science
The paper establishes the nature of the redistribution of chemical elements and their concentration in secondary surface structures for the material systems “steel 45XN2MFA-grease-BrOTsS4-4-2.5”, “steel 45XN2MFA-grease-BrOTsS4-4-4”, “steel 45XN2MFA-grease-L-63 ”, tested under the conditions of simulating film starvation when lubricated with 15W40 Lukoil-Super SAE SG/CD engine oil. Since the formula obtained by us includes the Gibbs energy, the self-organization of the structure under consideration naturally also enters. General laws of self-organization are observed when a number of conditions are met: irreversibility, openness (nonequilibrium), nonlinearity, instability (coherence), dissipativity. All these elements were observed and described by us in this work. It is due to self-organization that the distribution of chemical elements carbon and oxygen occurred on the surfaces L63 and BrOF4-4-4. To this effect must be added a decrease in the surface tension of the lubricant.

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