Open AccessFabrication of 3D surface-enhanced Raman scattering (SERS) substrate via solid-state dewetting of sputtered gold on fumed silica surface
Author(s) -
Panuwat Pengphorm,
P. Nuchuay,
N. Boonrod,
Sirawit Boonsit,
Panuwat Srisamran,
Sukrit Thongrom,
P. Pewkum,
Pruet Kalasuwan,
Paphavee van Dommelen,
Chalongrat Daengngam
Publication year - 2021
Publication title -
journal of physics. conference series
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.21
H-Index - 85
eISSN - 1742-6596
pISSN - 1742-6588
DOI - 10.1088/1742-6596/1719/1/012082
Subject(s) - materials science , dewetting , raman spectroscopy , raman scattering , sputtering , substrate (aquarium) , optoelectronics , surface enhanced raman spectroscopy , fabrication , thin film , nanotechnology , analytical chemistry (journal) , optics , chemistry , medicine , oceanography , physics , alternative medicine , pathology , geology , chromatography
Raman spectroscopy is a potent and widespread optical analytical technique thanks to its non-invasive and high-specification for the detection of targeted molecules. However, for the case of trace detection, it is common that a weak Raman signal is easily swamped by noise and thus unable to be resolved. Here, we demonstrated a facile fabrication of a three-dimensional surface enhanced Raman spectroscopy (SERS) substrate, based on low-vacuum sputtering of gold nanofilm on hierarchically rough fumed silica monolayers deposited by layer-by-layer self-assembly technique. Due to the much lower surface energy of the silica-air heterostructure compared to metallic materials, deposited gold layers dewetted the surface spontaneously, forming nano-sized spherical gold particles without the requirement of an extra annealing process. Plasmonic effects were studied through optical absorption measurements, while the surface morphology and topography were examined using SEM and AFM for various sputtering durations. Furthermore, the enhancement of Raman spectrum was investigated for 10 −4 M of methylene blue (MB), using 532 nm and 0.57 mW excitation laser. An initial Raman enhancement factor of 17 was observed at 1645 cm −1 peak, even with yet to be optimized fabrication procedures.