Open AccessPotentiometric determination of nickel (II) with sodium diethyldithiocarbamate (NaDEDC)
Author(s) -
A M Zakharkiva,
S. V. Shumar
Publication year - 2020
Publication title -
journal of physics. conference series
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.21
H-Index - 85
eISSN - 1742-6596
pISSN - 1742-6588
DOI - 10.1088/1742-6596/1611/1/012028
Subject(s) - potentiometric titration , chemistry , reagent , nickel , equivalence point , inorganic chemistry , titration , electroanalytical method , gran plot , electrode , metal ions in aqueous solution , sodium , ion , organic chemistry
The article presents the results of potentiometric titration of the solution containing Ni (II) by the solution of sodium diethylditheocarbamate (NaDEDC). The possibilities of carbon composite electrode (CCE) and certain ion-selective and metal electrodes as the sensors for potentiometric determination of ions were investigated. The conditions for potentiometric titration of nickel (reagent, pH, composition of supporting solution, efficient electrode, effect of interfering ions) using sensors have been studied and optimized. The titration curves were processed by the linearization method which provide determination of equivalence point with high accuracy.