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The Effect of Ce-doping Molar Concentration with Silica Xerogel on the Materials Optical Properties
Author(s) -
Abdul-Jabbar Abbas Oudh,
Asia H. Al-Mashhadani,
Wesam A. A. Twej
Publication year - 2019
Publication title -
journal of physics. conference series
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.21
H-Index - 85
eISSN - 1742-6596
pISSN - 1742-6588
DOI - 10.1088/1742-6596/1279/1/012043
Subject(s) - cerium , materials science , photoluminescence , ionic bonding , inert gas , tetragonal crystal system , doping , porosity , atmosphere (unit) , sol gel , reducing atmosphere , chemical engineering , analytical chemistry (journal) , ion , composite material , chemistry , nanotechnology , crystal structure , metallurgy , crystallography , organic chemistry , physics , optoelectronics , engineering , thermodynamics
Ionic cerium-doped pure silica glass with high photoluminescence, has been prepared using the sol–gel technique and densification of the porous xerogel under inert and air atmosphere.The present study shows the effect of densification atmosphere and molar concentrations on the optical properties of ionic cerium-activated silica glasses.Moreover, the PL intensity increased with increasing the molar concentration of ionic Ce+3.The PL is composed of two sub-bandsascribable to tetragonal distortion of the matrix and spin–orbit coupling but these sub-bands arecloser to each other when the core rod is densified under inert atmosphere.

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