Open AccessSynthesis and Characterization of new Manganese(II), Cobalt(II), Cadmium(II) and Mercury(II) Complexes with ligand [N-(3-acetylphenylcarbamothioyl)-2-chloroacetamide] and their Antibacterial Studies
Author(s) -
Enass J. Waheed,
Murtadha Abd Ali Farhan,
Ghusoon Faidhi Hameed
Publication year - 2019
Publication title -
journal of physics. conference series
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.21
H-Index - 85
eISSN - 1742-6596
pISSN - 1742-6588
DOI - 10.1088/1742-6596/1234/1/012096
Subject(s) - chemistry , cobalt , ligand (biochemistry) , manganese , denticity , octahedral molecular geometry , cadmium , octahedron , inorganic chemistry , mercury (programming language) , metal , metal ions in aqueous solution , medicinal chemistry , nuclear chemistry , crystallography , organic chemistry , crystal structure , biochemistry , programming language , receptor , computer science
Addition chloro acetyl isothiocyanate (C 3 H 2 ClNOS) with 3-Aminoaceto phenone (C 8 H 9 NO) to prepare a fresh Ligand [N-(3-acetyl phenyl carbamothioyl)-2-chloroacetamide](L). The ligand (L) behaves as bidentate coordinating through O and S donor with metal ions, the general formula of all complexes [M(L) 2 (Cl) 2 ](M +2 = Manganese(II), Cobalt(II), Cadmium(II) and Mercury(II)). Compounds were investigation by Proton-1, Carbon -13 NMR spectra (ligand (L) only), Element Microanalysis for C, N, H, O, S, Fourier-transform infrared, UV visible, Conductance, Magnetic susceptibility and Atomic Absorption (A.A). Based on spectral data, complexes appear octahedral geometry. The anti-bacterial activity of the complexes against two type of bacterial was higher than for free ligand.