Open AccessSynthesis and Characterization of Fe(III) Complex with N’- (3-Nitrobenzoyl)Isonicotinohydrazide as an Anti-tuberculosis Candidate
Author(s) -
Ruswanto Ruswanto,
Y Sarwatiningsih,
Atk Pratita,
Indra Indra,
Rishe Purnama Dewi
Publication year - 2019
Publication title -
journal of physics. conference series
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.21
H-Index - 85
eISSN - 1742-6596
pISSN - 1742-6588
DOI - 10.1088/1742-6596/1179/1/012136
Subject(s) - chemistry , atomic absorption spectroscopy , metal , infrared spectroscopy , nuclear chemistry , fourier transform infrared spectroscopy , infrared , ligand (biochemistry) , absorption (acoustics) , analytical chemistry (journal) , stereochemistry , materials science , organic chemistry , physics , quantum mechanics , optics , biochemistry , receptor , composite material
Recently, we have been conducted synthesis of complex compounds of Fe(III)N’-(3- nitrobenzoyl)isonicotinohydrazideusing refluxing N’-(3 -nitrobenzoyl)isonicotinohydrazideas ligands and FeCl 3 .6H 2 O as the metal at 75 °C for 6 hours in ethanol. The synthesis results obtained82.45% recovery, and from the purity test are shown with a narrow melting range is 220-222°C. Based on identification with UV-Visible spectrophotometer, infrared spectrometer and Atomic Absorption Spectrophotometer (AAS) indicate that the complex compound have λ max of 272.00 nm, giving vibration of Fe-O at 495.1 cm −1 and 599.6 cm −1 with formula complex compounds, namely [Fe(C 13 H 10 N 4 O 4 (H 2 O) 4 )Cl 3 ].10 H 2 O.