Open AccessTDPAC andβ-NMR applications in chemistry and biochemistry
Author(s) -
Attila Jancsó,
J. G. Correia,
A. Gottberg,
Juliana Schell,
Monika Stachura,
Dániel Szunyogh,
S. Pallada,
Doru C. Lupascu,
Magdalena Kowalska,
Lars Hemmingsen
Publication year - 2017
Publication title -
journal of physics. g, nuclear and particle physics
Language(s) - English
Resource type - Journals
eISSN - 1361-6471
pISSN - 0954-3899
DOI - 10.1088/1361-6471/aa666b
Subject(s) - nuclear magnetic resonance spectroscopy , spectroscopy , chemistry , physics , instrumentation (computer programming) , nanotechnology , analytical chemistry (journal) , chemical physics , materials science , nuclear magnetic resonance , environmental chemistry , computer science , quantum mechanics , operating system
Time differential perturbed angular correlation (TDPAC) of γ-rays spectroscopy has been applied in chemistry and biochemistry for decades. Herein we aim to present a comprehensive review of chemical and biochemical applications of TDPAC spectroscopy conducted at ISOLDE over the past 15 years, including elucidation of metal site structure and dynamics in proteins and model systems. β-NMR spectroscopy is well established in nuclear physics, solid state physics, and materials science, but only a limited number of applications in chemistry have appeared. Current endeavors at ISOLDE advancing applications of β-NMR towards chemistry and biochemistry are presented, including the first experiment on (31)Mg(2+) in an ionic liquid solution. Both techniques require the production of radioisotopes combined with advanced spectroscopic instrumentation present at ISOLDE