Comparison of effective conductivities calculated by the effective medium approximation and the self consistent approximation for core-shell particulate composites
Author(s) -
George R. Gavalas
Publication year - 2017
Publication title -
aip advances
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.421
H-Index - 58
ISSN - 2158-3226
DOI - 10.1063/1.4999331
Subject(s) - volume fraction , shell (structure) , particle (ecology) , materials science , core (optical fiber) , conductivity , simple (philosophy) , composite material , matrix (chemical analysis) , physics , quantum mechanics , philosophy , epistemology , oceanography , geology
The effective conductivity of composites containing simple or core-shell particles has been estimated in the literature using the Mean Field Approximation (MFA) and the Self-Consistent Approximation (SCA) among other techniques. It is shown here that for both simple and core-shell particles the two approximations agree to first order in the particle volume fraction but differ at the second order term. For simple particles the coefficient of the second order term calculated by SCA is at much better agreement with previous exact results than the coefficient calculated by MFA. For core-shell particles the results of the two approximations are almost identical up to particle volume fraction 0.20 but diverge with increasing volume fraction and particle-to-matrix conductivity ratio
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