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Study of polymeric nanocomposites prepared by inserting graphene and / or Ag, Au and ZnO nanoparticles in a TEGDA polymer matrix, by means of the use of dielectric spectroscopy
Author(s) -
Valeria Alzari,
Daniele Nuvoli,
Vanna Sanna,
T. Caruso,
Salvatore Marino,
N. Scaramuzza
Publication year - 2016
Publication title -
aip advances
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.421
H-Index - 58
ISSN - 2158-3226
DOI - 10.1063/1.4943672
Subject(s) - nanocomposite , materials science , graphene , dielectric spectroscopy , dielectric , nanoparticle , polymer , relaxation (psychology) , polymer nanocomposite , composite material , conductivity , chemical engineering , polymer chemistry , electrochemistry , nanotechnology , electrode , chemistry , optoelectronics , engineering , psychology , social psychology
Polymeric nanocomposites were prepared by inserting graphene and/or Ag, Au and ZnO nanoparticles in a TEGDA (tetraethyleneglycol diacrylate) polymer matrix. The polymeric films were characterized in terms of their dielectric properties by electrochemical impedance spectroscopy. The impedance data were fitted by generalized relaxation functions in order to determine conductivity, dielectric response and molecular relaxation time of the nanocomposite films. In particular, a stretched exponential function, Kohlrausch-Williams-Watts function (KWW), was used to investigate polymer/graphene/metal nanocomposites

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