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Structural determination of argon trimer
Author(s) -
Xiguo Xie,
Chengyin Wu,
Ying Yuan,
Xin-Zheng Li,
Cong Wu,
Peng Wang,
Yongkai Deng,
Yunquan Liu,
Qihuang Gong
Publication year - 2015
Publication title -
aip advances
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.421
H-Index - 58
ISSN - 2158-3226
DOI - 10.1063/1.4932041
Subject(s) - trimer , argon , ionization , fragmentation (computing) , ab initio quantum chemistry methods , ab initio , atomic physics , coulomb explosion , molecular physics , materials science , chemistry , physics , molecule , nuclear magnetic resonance , dimer , computer science , ion , operating system , organic chemistry
Rare gas clusters are model systems to investigate structural properties at finite size. However, their structures are difficult to be determined with available experimental techniques because of the strong coupling between the vibration and the rotation. Here we experimentally investigated multiple ionization and fragmentation dynamics of argon trimer by ultrashort intense laser fields and reconstructed their structures with Coulomb explosion technique. The measured structure distribution was compared with our finite-temperature ab initio calculations and the discrepancy was discussed. The present study provides a guidance for the development of theoretical methods for exploring the geometric structure of rare gas clusters

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