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Orbital molecules in electronic materials
Author(s) -
J. Paul Attfield
Publication year - 2015
Publication title -
apl materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.571
H-Index - 60
ISSN - 2166-532X
DOI - 10.1063/1.4913736
Subject(s) - molecule , materials science , chemical physics , singlet state , electron configuration , atom (system on chip) , metal , electronic structure , non bonding orbital , electron , ion , condensed matter physics , molecular orbital , atomic physics , nanotechnology , physics , excited state , quantum mechanics , computer science , embedded system , metallurgy
Orbital molecules are made up of coupled orbital states on several metal ions within an orbitally ordered (and sometimes also charge-ordered) solid such as a transition metal oxide. Spin-singlet dimers are known in many materials, but recent discoveries of more exotic species such as 18-electron heptamers in AlV2O4 and magnetic 3-atom trimerons in magnetite (Fe3O4) have shown that orbital molecules constitute a general new class of quantum electronic states in solids

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