Solvent-induced changes in PEDOT:PSS films for organic electrochemical transistors
Author(s) -
Shiming Zhang,
Prajwal Kumar,
Amel Sarah Nouas,
Laurie Fontaine,
Hao Tang,
Fabio Cicoira
Publication year - 2014
Publication title -
apl materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.571
H-Index - 60
ISSN - 2166-532X
DOI - 10.1063/1.4905154
Subject(s) - pedot:pss , materials science , conductive polymer , spin coating , electrochemistry , polymer , chemical engineering , organic semiconductor , solvent , doping , conductivity , coating , polymer chemistry , nanotechnology , optoelectronics , composite material , organic chemistry , electrode , chemistry , engineering
Organic electrochemical transistors based on the conducting polymer poly(3,4-ethylenedioxythiophene) doped with poly(styrenesulfonate) (PEDOT:PSS) are of interest for several bioelectronic applications. In this letter, we investigate the changes induced by immersion of PEDOT:PSS films, processed by spin coating from different mixtures, in water and other solvents of different polarities. We found that the film thickness decreases upon immersion in polar solvents, while the electrical conductivity remains unchanged. The decrease in film thickness is minimized via the addition of a cross-linking agent to the mixture used for the spin coating of the films
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