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Orientation specific deposition of mesoporous particles
Author(s) -
Tomas Kjellman,
Niklas Bodén,
Håkan Wennerström,
Karen J. Edler,
Viveka Alfredsson
Publication year - 2014
Publication title -
apl materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.571
H-Index - 60
ISSN - 2166-532X
DOI - 10.1063/1.4897282
Subject(s) - materials science , mesoporous material , sonication , dispersion (optics) , chemical engineering , mesoporous silica , deposition (geology) , particle (ecology) , aqueous solution , evaporation , relative humidity , nanotechnology , composite material , optics , catalysis , chemistry , organic chemistry , paleontology , physics , oceanography , thermodynamics , sediment , engineering , biology , geology
We present a protocol for a facile orientation specific deposition of plate-like mesoporous SBA-15 silica particles onto a surface (mesopores oriented normal to surface). A drop of an aqueous dispersion of particles is placed on the surface and water vaporizes under controlled relative humidity. Three requirements are essential for uniform coverage: particle dispersion should not contain aggregates, a weak attraction between particles and surface is needed, and evaporation rate should be low. Aggregates are removed by stirring/sonication. Weak attraction is realized by introducing cationic groups to the surface. Insight into the mechanisms of the so-called coffee stain effect is also provided

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