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Al and Fe co-doped transparent conducting ZnO thin film for mediator-less biosensing application
Author(s) -
Shibu Saha,
Vinay Gupta
Publication year - 2011
Publication title -
aip advances
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.421
H-Index - 58
ISSN - 2158-3226
DOI - 10.1063/1.3654497
Subject(s) - glucose oxidase , biosensor , materials science , doping , cyclic voltammetry , thin film , conductivity , layer (electronics) , chemical engineering , electrode , analytical chemistry (journal) , electrochemistry , nanotechnology , chemistry , optoelectronics , chromatography , engineering
Highly c-axis oriented Al and Fe co-doped ZnO (ZAF) thin film is prepared by pulsed laser deposition. Fe introduces redox centre along with shallow donor level while Al doping enhances conductivity of ZnO, thus removing the requirement of both mediator and bottom conducting layer in bioelectrode. Model enzyme (glucose oxidase), was immobilized on surface of ZAF matrix. Cyclic voltammetry and photometric assay show that prepared bio-electrode is sensitive to glucose concentration with enhanced response of 0.18 μAmM-1cm-2 and low Km ∼ 2.01 mM. The results illustrate that ZAF is an attractive matrix for realization of miniaturized mediator-less solid state biosensor

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