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Self-organized phase segregation between inorganic nanocrystals and PC61BM for hybrid high-efficiency bulk heterojunction photovoltaic cells
Author(s) -
SaiWing Tsang,
Huiying Fu,
Jianying Ouyang,
Yanguang Zhang,
Kui Yu,
Jianping Lu,
Ye Tao
Publication year - 2010
Publication title -
applied physics letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.182
H-Index - 442
eISSN - 1077-3118
pISSN - 0003-6951
DOI - 10.1063/1.3454923
Subject(s) - materials science , photovoltaic system , heterojunction , hybrid solar cell , nanocrystal , phase (matter) , energy conversion efficiency , polymer solar cell , optoelectronics , composite number , layer (electronics) , quantum dot solar cell , nanotechnology , chemical engineering , composite material , chemistry , organic chemistry , ecology , biology , engineering
We demonstrate a simple approach to generate phase segregation between colloidal PbS nanocrystals (NCs) and organic [6,6]-phenyl C\u2086\u2081 butyric acid methyl ester (PC\u2086\u2081BM). Continuous vertical phase segregation is observed in cross-linked composite films of NCs and PC\u2086\u2081BM. Hybrid bulk heterojunction photovoltaic cells fabricated with the phase segreated composite layer have achieved the state-of-art power conversion efficiency of 3.7% under one sun of simulated Air Mass 1.5 Global solar irradiation. The presented method can be generally applied in other NC/organic systems for the development of hybrid heterojunction photovoltaic cells.Peer reviewed: YesNRC publication: Ye

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