Intermolecular Cycloaddition of Ethyl Glyoxylate O-tert-Butyldimethylsilyloxime with Alkenes | Zendy

Osamu Tamura | Zendy; Hiroyuki Ishibashi | Zendy; Nobuyoshi Morita | Zendy; Yuu Takano | Zendy; Kenji Fukui | Zendy; Iwao Okamoto | Zendy; Xin Huang | Zendy; Yoshiyuki Tsutsumi | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Intermolecular Cycloaddition of Ethyl Glyoxylate O-tert-Butyldimethylsilyloxime with Alkenes

Author(s) -

Osamu Tamura,

Hiroyuki Ishibashi,

Nobuyoshi Morita,

Yuu Takano,

Kenji Fukui,

Iwao Okamoto,

Xin Huang,

Yoshiyuki Tsutsumi

Publication year - 2007

Publication title -

synlett

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.712

H-Index - 133

eISSN - 1437-2096

pISSN - 0936-5214

DOI - 10.1055/s-2007-967939

Subject(s) - chemistry , glyoxylate cycle , cycloaddition , intermolecular force , medicinal chemistry , stereochemistry , organic chemistry , catalysis , molecule , enzyme

Ethyl glyoxylate O-tert-butyldimethylsilyloxime, on treatment with various alkenes in the presence of BF3·OEt2, generated a C-ethoxycarbonyl N-boranonitrone intermediate, which underwent intermolecular cycloaddition to afford 3-(ethoxycarbonyl)isoxazolidines in moderate to high yields. © Georg Thieme Verlag Stuttgart

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research