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Synthesis and characterisation of SAPO‐34 with high surface area
Author(s) -
Bai Yadong,
Zheng Jiajun,
Fan Binbin
Publication year - 2015
Publication title -
micro and nano letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.25
H-Index - 31
ISSN - 1750-0443
DOI - 10.1049/mnl.2015.0101
Subject(s) - materials science , nanotechnology
SAPO‐34 molecular sieve with a high surface area has been successfully synthesised using Y5669 (N‐[3‐(trimethoxysilyl)propy]aniline) functionalised fumed, silica as the silica source and tetraethylammonium hydroxide as a structure directing agent via a 60‐day crystallisation time. X‐ray diffraction result indicates that the sample is highly crystalline SAPO‐34 and the scanning electron (electron) microscopy images show that the sample is nanosized with a size of ca. 200 nm. N 2 adsorption and ammonia temperature‐programmed adsorption results indicate that the synthesised SAPO‐34 sample exhibits a much higher microporous area and stronger acidity than the conventional SAPO‐34. Moreover, the microporous surface area of the as‐obtained SAPO‐34 can reach 835 m 2 g −1 , which is difficult to realise using other synthesis methods.

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