Preparation and electrochemical behaviour study of layered Bi 2 SrTa 2 O 9  with a cationic manganese porphyrin | Zendy

Tao Tiantian | Zendy; Zhang Xiaobo | Zendy; Liu Lin | Zendy; Ma Juanjuan | Zendy; Zhang Dongen | Zendy; Pan Binbin | Zendy; Tong Zhiwei | Zendy

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Preparation and electrochemical behaviour study of layered Bi 2 SrTa 2 O 9 with a cationic manganese porphyrin

Author(s) -

Tao Tiantian,

Zhang Xiaobo,

Liu Lin,

Ma Juanjuan,

Zhang Dongen,

Pan Binbin,

Tong Zhiwei

Publication year - 2014

Publication title -

micro and nano letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.25

H-Index - 31

ISSN - 1750-0443

DOI - 10.1049/mnl.2014.0496

Subject(s) - manganese , porphyrin , cationic polymerization , electrochemistry , materials science , chemistry , inorganic chemistry , crystallography , nanotechnology , photochemistry , polymer chemistry , electrode , metallurgy

Layered Bi 2 SrTa 2 O 9 was achieved by solid‐phase synthesis and then cationic metalloporphyrin 5,10,15,20‐tetrakis(N‐methylpyridinium‐4‐yl) porphyrinato manganese (MnTMPyP), was intercalated into layered material Bi 2 SrTa 2 O 9 by a guest‐exchange method using n ‐PrNH 3 + ‐SrTa 2 O 7 as a precursor. The new intercalation multicomposite MnTMPyP‐SrTa 2 O 7 was characterised using X‐ray diffraction, infrared and scanning electron micrograph images. Moreover, the MnTMPyP‐SrTa 2 O 7 nanocomposite exhibited fine electrocatalytic activity towards oxygen reduction.

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