Open AccessSolvothermal synthesis of uniform Li 3 V 2 (PO 4 ) 3 /C nanoparticles as cathode materials for lithium ion batteries
Author(s) -
He Wenxiang,
Chen Qingyuan,
Zhang Tianren,
Gao Yunfang,
Cao Jin
Publication year - 2015
Publication title -
micro and nano letters
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.25
H-Index - 31
ISSN - 1750-0443
DOI - 10.1049/mnl.2014.0325
Subject(s) - materials science , nanoparticle , lithium (medication) , solvothermal synthesis , cathode , particle size , chemical engineering , carbon fibers , transmission electron microscopy , scanning electron microscope , nanotechnology , composite material , composite number , chemistry , endocrinology , engineering , medicine
A uniform precursor of Li 3 V 2 (PO 4 ) 3 nanoparticles was synthesised by a solvothermal method using ethanolamine lactate as both solvent and carbon sources at ambient pressure. Nanostructured Li 3 V 2 (PO 4 ) 3 /C cathode materials could be successfully prepared by subsequent heat treatment. The scanning and transmission electron microscopy observation shows that the as‐synthesised Li 3 V 2 (PO 4 ) 3 /C powders retained the morphology and the particle size of the precursor that was formed during the solvothermal process. The Li 3 V 2 (PO 4 ) 3 particles are coated with uniform carbon layers with a thickness of about 5 nm. The material presents excellent performance with a high‐rate capacity and cycle stability. It can deliver discharge capacities of 127.9, 117.7, 104.9 and 95.6 mAh g −1 in the potential ranges of 3.0–4.3 V, 164.0, 154.8, 141.0 and 131.1 mAh g −1 between 3.0 and 4.8 V corresponding to 0.5, 1, 5 and 10 C rate after cycles, respectively. The charge transfer impedance increases from 55.55 to 127.31 Ω after 50 cycles at 1.0 C, which is attributed to the refined structure and the uniform carbon film on the surface of the as‐prepared Li 3 V 2 (PO 4 ) 3 /C powders.