Amphiphilic peroxo polyoxometalate as reaction control phase transfer catalyst for efficient epoxidation of olefins | Zendy

Wu Jinghui | Zendy; Zheng Hongwei | Zendy; Wang Chi | Zendy; Wang Xianze | Zendy; Wang Xiaohong | Zendy; Huo Mingxin | Zendy

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Amphiphilic peroxo polyoxometalate as reaction control phase transfer catalyst for efficient epoxidation of olefins

Author(s) -

Wu Jinghui,

Zheng Hongwei,

Wang Chi,

Wang Xianze,

Wang Xiaohong,

Huo Mingxin

Publication year - 2021

Publication title -

micro and nano letters

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.25

H-Index - 31

ISSN - 1750-0443

DOI - 10.1049/mna2.12090

Subject(s) - polyoxometalate , catalysis , amphiphile , phase (matter) , chemistry , phase transfer catalyst , photochemistry , materials science , organic chemistry , copolymer , polymer

A peroxo polyoxometalate‐based catalyst was synthesized, characterized, and employed as a catalyst in the epoxidation of olefins with hydrogen peroxide (H 2 O 2 ). During the reaction, the insoluble catalyst became soluble and an emulsion formed to promote the epoxidation process. Then the emulsion broke and the catalyst precipitated for reuse easily.

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