Effects of temperature on chaotropic anion-induced shape transitions of star molecular bottlebrushes with heterografted poly(ethylene oxide) and poly(N,N-dialkylaminoethyl methacrylate) side chains in acidic water | Zendy

Evan M. Lewoczko | Zendy; Michael T. Kelly | Zendy; Ethan W. Kent | Zendy; Bin Zhao | Zendy

Open Access

Effects of temperature on chaotropic anion-induced shape transitions of star molecular bottlebrushes with heterografted poly(ethylene oxide) and poly(N,N-dialkylaminoethyl methacrylate) side chains in acidic water

Author(s) -

Evan M. Lewoczko,

Michael T. Kelly,

Ethan W. Kent,

Bin Zhao

Publication year - 2021

Publication title -

soft matter

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.99

H-Index - 170

eISSN - 1744-6848

pISSN - 1744-683X

DOI - 10.1039/d1sm00728a

Subject(s) - protonation , chaotropic agent , ethylene oxide , chemistry , ion , side chain , amine gas treating , polymer chemistry , lower critical solution temperature , oxide , crystallography , organic chemistry , polymer , copolymer

While super chaotropic anion (CA)-collapsed protonated tertiary amine-containing three-arm star bottlebrushes remain globular upon heating from room temperature to 70 °C, moderate CA-collapsed bottlebrushes exhibit star-globule shape transitions.

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