Open AccessAufbau vs. non-Aufbau ground states in two-coordinate d7 single-molecule magnets
Author(s) -
Dylan Errulat,
Katie L. M. Harriman,
Diogo A. Gálico,
Jeffrey S. Ovens,
Akseli Mansikkamäki,
Muralee Murugesu
Publication year - 2021
Publication title -
inorganic chemistry frontiers
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.421
H-Index - 55
eISSN - 2052-1553
pISSN - 2052-1545
DOI - 10.1039/d1qi00912e
Subject(s) - magnet , ground state , anisotropy , single molecule magnet , molecule , mixing (physics) , physics , atomic physics , chemistry , magnetic field , magnetization , quantum mechanics
Magnetic anisotropy is generated in two related d 7 single-molecule magnets; (1) via 3d-4s orbital mixing in Fe I ; and (2) a non-Aufbau ground state in Co II , demonstrating that the electronic configurations are large retained independent of geometry.