Halogen bonding effect on electrochemical anion oxidation in ionic liquids | Zendy

Marie Alvarez | Zendy; Cedric Houzé | Zendy; Sihem Groni | Zendy; Bernd Schöllhorn | Zendy; Claire Fave | Zendy

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Halogen bonding effect on electrochemical anion oxidation in ionic liquids

Author(s) -

Marie Alvarez,

Cedric Houzé,

Sihem Groni,

Bernd Schöllhorn,

Claire Fave

Publication year - 2021

Publication title -

organic and biomolecular chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.923

H-Index - 146

eISSN - 1477-0539

pISSN - 1477-0520

DOI - 10.1039/d1ob01031j

Subject(s) - halogen , electrochemistry , ionic liquid , ion , ionic bonding , chemistry , inorganic chemistry , halogen bond , electrode , organic chemistry , catalysis , alkyl

Three Ionic liquids (ILs) based on an imidazolium core have been compared and used as solvents for the oxidation of various anions. Electrochemical experiments as well as NMR titrations and X-ray diffraction analyses unambiguously confirm the crucial role of non-covalent halogen bonding on the oxidation potentials and consequently the electrochemical window of the respective ILs.

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