Open AccessA paradigm for the efficient synthesis of bio-based polycarbonate with deep eutectic solvents as catalysts by inhibiting the degradation of molecular chains
Author(s) -
Weiwei Wang,
Zifeng Yang,
Yaqin Zhang,
Hongyan He,
Wenjuan Fang,
Zhencai Zhang,
Fengyuan Xu
Publication year - 2021
Publication title -
green chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.221
H-Index - 221
eISSN - 1463-9270
pISSN - 1463-9262
DOI - 10.1039/d1gc01150b
Subject(s) - depolymerization , polycarbonate , eutectic system , catalysis , degradation (telecommunications) , isosorbide , carbonate , chemistry , macromolecule , chemical engineering , materials science , combinatorial chemistry , organic chemistry , polymer chemistry , computer science , telecommunications , biochemistry , alloy , engineering
A catalytic system composed of deep eutectic solvents (DESs) with adjustable pH was developed for the efficient synthesis of poly(isosorbide) carbonate with high molecular weight by inhibiting the depolymerization of macromolecular chains.