Remote control: stereoselective coordination of electron-deficient 2,2′-bipyridine ligands to Re(i) and Ir(iii) cores | Zendy

Kimberley Jerwood | Zendy; Phoebe Lowy | Zendy; Laura Deeming | Zendy; Benson M. Kariuki | Zendy; Paul D. Newman | Zendy

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Remote control: stereoselective coordination of electron-deficient 2,2′-bipyridine ligands to Re(i) and Ir(iii) cores

Author(s) -

Kimberley Jerwood,

Phoebe Lowy,

Laura Deeming,

Benson M. Kariuki,

Paul D. Newman

Publication year - 2021

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/d1dt02928b

Subject(s) - stereoselectivity , chemistry , substituent , cationic polymerization , stereochemistry , derivative (finance) , bipyridine , ligand (biochemistry) , crystallography , receptor , polymer chemistry , organic chemistry , crystal structure , biochemistry , catalysis , financial economics , economics

Configurational diastereoselectivity is observed upon coordination of a mono-substituted bipy ligand with an asymmetric amidinium group at the 4-position while no selectivity occurs with the analogous 5-derivative.

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