Open AccessRemote control: stereoselective coordination of electron-deficient 2,2′-bipyridine ligands to Re(i ) and Ir(iii ) cores
Author(s) -
Kimberley Jerwood,
Phoebe Lowy,
Laura Deeming,
Benson M. Kariuki,
Paul D. Newman
Publication year - 2021
Publication title -
dalton transactions
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.98
H-Index - 184
eISSN - 1477-9234
pISSN - 1477-9226
DOI - 10.1039/d1dt02928b
Subject(s) - stereoselectivity , chemistry , substituent , cationic polymerization , stereochemistry , derivative (finance) , bipyridine , ligand (biochemistry) , crystallography , receptor , polymer chemistry , organic chemistry , crystal structure , biochemistry , catalysis , financial economics , economics
Configurational diastereoselectivity is observed upon coordination of a mono-substituted bipy ligand with an asymmetric amidinium group at the 4-position while no selectivity occurs with the analogous 5-derivative.