Microscopic insights into long-range 1D ordering in a dense semi-disordered molecular overlayer | Zendy

Ryan T. Hannagan | Zendy; Isaac G. Onyango | Zendy; Amanda M. Larson | Zendy; JeanSabin McEwen | Zendy; E. Charles H. Sykes | Zendy

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Microscopic insights into long-range 1D ordering in a dense semi-disordered molecular overlayer

Author(s) -

Ryan T. Hannagan,

Isaac G. Onyango,

Amanda M. Larson,

JeanSabin McEwen,

E. Charles H. Sykes

Publication year - 2021

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/d1cc01574e

Subject(s) - overlayer , chemical physics , materials science , phase (matter) , scanning tunneling microscope , range (aeronautics) , molecule , propene , crystallography , condensed matter physics , nanotechnology , chemistry , physics , biochemistry , organic chemistry , composite material , catalysis

The formation of a two-phase surface molecular overlayer that transitions from isolated propene molecules to a highly ordered 1D chain structure on Cu(111) is elucidated through combined high-resolution STM imaging and DFT-based calculations. These models reveal how disordered molecules present in-between the 1D chains stabilizes the system as a whole.

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