Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes | Zendy

Luis M. Aguirre Quintana | Zendy; Ningxin Jiang | Zendy; John Bacsa | Zendy; Henry S. La Pierre | Zendy

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Coinage metal tris(dialkylamido)imidophosphorane complexes as transmetallation reagents for cerium complexes

Author(s) -

Luis M. Aguirre Quintana,

Ningxin Jiang,

John Bacsa,

Henry S. La Pierre

Publication year - 2020

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/d0dt00842g

Subject(s) - transmetalation , tris , cerium , reagent , chemistry , metal , inorganic chemistry , organic chemistry , catalysis , biochemistry

We report the synthesis of tetrameric Cu(i) and Ag(i) homoleptic complexes supported by the tris(piperidinyl)imidophosphorane [NP(pip) 3 ] 1- and [NP(1,2-bis- Bu-diamidoethane)(NE 2 )] 1- ligands. These complexes demonstrate the redox stability of the imidophosphorane ligands to oxidizing salts, and the silver complexes can, in turn, serve as oxidative transmetallation reagents for the isolation of tetravalent cerium complexes from cerium metal or trivalent cerium precursors.

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