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Flexible to rigid: IR spectroscopic investigation of a rhenium-tricarbonyl-complex at a buried interface
Author(s) -
Kerstin Oppelt,
Laurent Sévery,
Mirjam Utters,
S. David Tilley,
Peter Hamm
Publication year - 2021
Publication title -
physical chemistry chemical physics/pccp. physical chemistry chemical physics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.053
H-Index - 239
eISSN - 1463-9084
pISSN - 1463-9076
DOI - 10.1039/d0cp06546c
Subject(s) - rhenium , interface (matter) , infrared , materials science , chemistry , optics , inorganic chemistry , molecule , physics , organic chemistry , gibbs isotherm
Immobilized rhenium tricarbonyl complexes were embedded in ALD deposited ZrO 2 , and investigated by (time resolved) infrared spectroscopy. The initially solvent exposed molecules react on the change of their environment.