Open AccessTurning on solid-state phosphorescence of platinum acetylides with aromatic stacking
Author(s) -
William J. Mullin,
Huan Qin,
Tomoyasu Mani,
Péter Müller,
Matthew J. Panzer,
Samuel W. Thomas
Publication year - 2020
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/d0cc02119a
Subject(s) - phosphorescence , platinum , stacking , solid state , photochemistry , chemistry , organic chemistry , catalysis , fluorescence , optics , physics
Neat solids that phosphoresce under ambient conditions are rare due to aggregation-caused quenching. This communication describes a platinum acetylide (PtPE) that phosphoresces as a solid due to programmed aromatic stacking interactions of pendant groups that prevent intermolecular aggregation.
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