Mg2+ ion-catalyzed polymerization of 1,3-dioxolane in battery electrolytes | Zendy

Emily Sahadeo | Zendy; Yang Wang | Zendy; ChuanFu Lin | Zendy; Yue Li | Zendy; Gary W. Rubloff | Zendy; Sang Bok Lee | Zendy

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Mg²⁺ ion-catalyzed polymerization of 1,3-dioxolane in battery electrolytes

Author(s) -

Emily Sahadeo,

Yang Wang,

ChuanFu Lin,

Yue Li,

Gary W. Rubloff,

Sang Bok Lee

Publication year - 2020

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/d0cc01769h

Subject(s) - dioxolane , polymerization , ion , electrolyte , catalysis , chemistry , polymer chemistry , battery (electricity) , inorganic chemistry , medicinal chemistry , organic chemistry , polymer , physics , electrode , power (physics) , quantum mechanics

Electrolyte salts with Mg2+ and Al3+ Lewis acidic cations demonstrate polymerization of 1,3-dioxolane. The speed and extent of the reaction depends on coordination of the anion with the Mg2+ cation catalyst. Weakly coordinating anions such as TFSI- aid faster polymerization while strongly coordinating anions such as ClO4- hinder the polymerization.

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