Assessing the impacts of dynamic soft-templates innate to switchable ionic liquids on nanoparticulate green rust crystalline structures | Zendy

Jian Zheng | Zendy; XiaoYing Yu | Zendy; ManhThuong Nguyen | Zendy; David Lao | Zendy; Yifeng Zhu | Zendy; Feng Wang | Zendy; David J. Heldebrant | Zendy

Open Access

Assessing the impacts of dynamic soft-templates innate to switchable ionic liquids on nanoparticulate green rust crystalline structures

Author(s) -

Jian Zheng,

XiaoYing Yu,

ManhThuong Nguyen,

David Lao,

Yifeng Zhu,

Feng Wang,

David J. Heldebrant

Publication year - 2019

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c9cc04581c

Subject(s) - template , ionic liquid , ionic bonding , rust (programming language) , nanotechnology , materials science , chemical engineering , chemistry , computer science , ion , organic chemistry , engineering , catalysis , programming language

This experimental and theoretical study investigates how dynamic solvation environments in switchable ionic liquids regulate the composition of nanoparticulate green rust. A custom microfluidic device enables in situ X-ray absorption spectroscopy to elucidate characterization of the solvent structure and speciation of reaction intermediates of air-sensitive nanoparticles growing in solution.

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