Hydrogen bonding between hydroxylic donors and MLCT-excited Ru(bpy)2(bpz)2+ complex: implications for photoinduced electron–proton transfer | Zendy

Sergei V. Lymar | Zendy; Gerald F. Manbeck | Zendy; Dmitry E. Polyansky | Zendy

Open Access

Hydrogen bonding between hydroxylic donors and MLCT-excited Ru(bpy)₂(bpz)²⁺ complex: implications for photoinduced electron–proton transfer

Author(s) -

Sergei V. Lymar,

Gerald F. Manbeck,

Dmitry E. Polyansky

Publication year - 2019

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c9cc01896d

Subject(s) - proton , excited state , photochemistry , chemistry , proton coupled electron transfer , electron transfer , hydrogen bond , hydrogen , electron , electron donor , irradiation , atomic physics , molecule , catalysis , nuclear physics , physics , organic chemistry

The equilibrium constants of the hydrogen bonding (HB) between hydroxylic donors, ROH, and an MLCT-excited Ru(bpy) 2 (bpz) 2+ complex, 1(T), correlated with ROH empirical HB acidities, which could be used for evaluating the unimolecular rate constants of concerted electron-proton transfer within the H-bonded phenol-1(T) exciplexes.

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