In situatomic-scale observation of inhomogeneous oxide reduction
Author(s) -
Xiaobo Chen,
Dongxiang Wu,
Lianfeng Zou,
Qiyue Yin,
Hanlei Zhang,
Dmitri N. Zakharov,
Eric A. Stach,
Guangwen Zhou
Publication year - 2018
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/c8cc03822h
Subject(s) - in situ , atomic units , scale (ratio) , reduction (mathematics) , oxide , materials science , chemistry , analytical chemistry (journal) , physics , metallurgy , environmental chemistry , mathematics , geometry , organic chemistry , quantum mechanics
We report in situ atomic-scale transmission electron microscopy observations of the surface dynamics during Cu2O reduction. We show inhomogeneous oxide reduction caused by the preferential adsorption of hydrogen at step edges that induces oxygen loss and destabilizes Cu atoms within the step edge, thereby resulting in the retraction motion of atomic steps at the oxide surface.
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