Solvent-dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]2 | Zendy

John B. Brazier | Zendy; Mark A. Newton | Zendy; Elena Barreiro | Zendy; Luis A. Adrio | Zendy; Leticia Naya | Zendy; King Kuok Hii | Zendy

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Solvent-dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]₂

Author(s) -

John B. Brazier,

Mark A. Newton,

Elena Barreiro,

Luis A. Adrio,

Leticia Naya,

King Kuok Hii

Publication year - 2017

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/c7dt01019b

Subject(s) - extended x ray absorption fine structure , solvent , chemistry , spectroscopy , palladium , catalysis , mass spectrometry , nuclear magnetic resonance spectroscopy , absorption spectroscopy , crystallography , absorption (acoustics) , inorganic chemistry , materials science , stereochemistry , organic chemistry , physics , optics , chromatography , quantum mechanics , composite material

The nuclearity and structures of the palladium complex [(SPhos)Pd(Ph)Cl] 2 in the solid and solution states are revisited using a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, NMR spectroscopy, mass spectrometry, DFT calculations and trapping experiments. The complex was tested for its catalytic activity in the coupling reaction between chlorobenzene and n-hexylamine, where different deactivation behaviours were observed in toluene, 1,4-dioxane and DMF.

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