A new Pu(iii) coordination geometry in (C5H5NBr)2[PuCl3(H2O)5]·2Cl·2H2O as obtained via supramolecular assembly in aqueous, high chloride media | Zendy

Robert G. Surbella | Zendy; Lucas C. Ducati | Zendy; Kristi L. Pellegrini | Zendy; Bruce K. McNamara | Zendy; Jochen Autschbach | Zendy; Jon M. Schwantes | Zendy; Christopher L. Cahill | Zendy

Open Access

A new Pu(iii) coordination geometry in (C₅H₅NBr)₂[PuCl₃(H₂O)₅]·2Cl·2H₂O as obtained via supramolecular assembly in aqueous, high chloride media

Author(s) -

Robert G. Surbella,

Lucas C. Ducati,

Kristi L. Pellegrini,

Bruce K. McNamara,

Jochen Autschbach,

Jon M. Schwantes,

Christopher L. Cahill

Publication year - 2017

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c7cc05988d

Subject(s) - halogen , chloride , hydrogen bond , crystallography , aqueous solution , evaporation , chemistry , ion , hydrogen , molecule , physics , alkyl , organic chemistry , thermodynamics

Crystals of a hydrated Pu(iii) chloride, (C 5 H 5 NBr) 2 [PuCl 3 (H 2 O) 5 ]·2Cl·2H 2 O, were grown via slow evaporation from acidic aqueous, high chloride media. X-ray diffraction data reveals the neutral [PuCl 3 (H 2 O) 5 ] tecton is assembled via charge assisted hydrogen and halogen bonds donated by 4-bromopyridinium cations and a series of inter-tecton hydrogen bonds.

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