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Poly(naphthalene diimide) vinylene: solid state red emission and semiconducting properties for transistors
Author(s) -
Xianfeng Liang,
Luxi Tan,
Zitong Liu,
Yanping Ma,
Guanxin Zhang,
Lin Wang,
Shayu Li,
Lichun Dong,
Jing Li,
Wei Chen
Publication year - 2017
Publication title -
chemical communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.837
H-Index - 333
eISSN - 1364-548X
pISSN - 1359-7345
DOI - 10.1039/c7cc01372h
Subject(s) - naphthalene , diimide , materials science , conjugated system , photochemistry , quantum yield , polymer , solid state , polymer chemistry , chemistry , molecule , organic chemistry , fluorescence , perylene , physics , quantum mechanics , composite material
In this work, a conjugated polymer PNV is developed, linking naphthalene diimide with a vinyl linkage. Owing to the C-HO hydrogen bond between the carbonyl and the vinyl, PNV exhibits a high red emission with a quantum yield of 33.4% in the solid state while it shows n-type properties with an electron mobility up to 1.5 × 10 -3 cm 2 V -1 s -1 in organic field effect transistors, simultaneously.

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