Pincer-plus-one ligands in self-assembly with palladium(ii): a molecular square and a molecular tetrahedron | Zendy

Ava Behnia | Zendy; Paul D. Boyle | Zendy; Mahmood Azizpoor Fard | Zendy; Johanna M. Blacquiere | Zendy; Richard J. Puddephatt | Zendy

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Pincer-plus-one ligands in self-assembly with palladium(ii): a molecular square and a molecular tetrahedron

Author(s) -

Ava Behnia,

Paul D. Boyle,

Mahmood Azizpoor Fard,

Johanna M. Blacquiere,

Richard J. Puddephatt

Publication year - 2016

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/c6dt04264c

Subject(s) - tetrahedron , pincer movement , square (algebra) , palladium , chemistry , self assembly , stereochemistry , crystallography , catalysis , mathematics , organic chemistry , geometry

The combination of a palladium(ii) precursor with a diimine-phenol ligand and an oxidant (H 2 O 2 or O 2 ) under different conditions has, serendipitously, given both a molecular square and a molecular tetrahedron by self-assembly of building blocks comprising palladium(ii) centres coordinated to the oxidised forms of the ligand.

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