Spontaneous aggregation of lithium ion coordination polymers in fluorinated electrolytes for high-voltage batteries | Zendy

Christos D. Malliakas | Zendy; Kevin Leung | Zendy; Krzysztof Z. Pupek | Zendy; Ilya A. Shkrob | Zendy; Daniel P. Abraham | Zendy

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Spontaneous aggregation of lithium ion coordination polymers in fluorinated electrolytes for high-voltage batteries

Author(s) -

Christos D. Malliakas,

Kevin Leung,

Krzysztof Z. Pupek,

Ilya A. Shkrob,

Daniel P. Abraham

Publication year - 2016

Publication title -

physical chemistry chemical physics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.053

H-Index - 239

eISSN - 1463-9084

pISSN - 1463-9076

DOI - 10.1039/c6cp01157h

Subject(s) - electrolyte , polymer electrolytes , lithium (medication) , ion , polymer , coordination polymer , inorganic chemistry , phase (matter) , chemistry , materials science , polymer chemistry , ionic conductivity , organic chemistry , electrode , medicine , endocrinology

Fluorinated carbonates are pursued as liquid electrolyte solvents for high-voltage Li-ion batteries. Here we report aggregation of [Li(+)(FEC)3]n polymer species in fluoroethylene carbonate containing electrolytes and scrutinize the causes for this behavior.

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