Crystalline-like structures and multilayering in Langmuir films of ionic liquids at the air–water interface | Zendy

Eduardo J. M. Filipe | Zendy; Pedro Morgado | Zendy; Miguel A. C. Teixeira | Zendy; Karina Shimizu | Zendy; Nathalie Bonatout | Zendy; Michel Goldmann | Zendy; José N. Cagia Lopes | Zendy

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Crystalline-like structures and multilayering in Langmuir films of ionic liquids at the air–water interface

Author(s) -

Eduardo J. M. Filipe,

Pedro Morgado,

Miguel A. C. Teixeira,

Karina Shimizu,

Nathalie Bonatout,

Michel Goldmann,

José N. Cagia Lopes

Publication year - 2016

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c6cc01368f

Subject(s) - langmuir , ionic bonding , interface (matter) , ionic liquid , chemical engineering , materials science , chemical physics , nanotechnology , chemistry , adsorption , ion , composite material , organic chemistry , contact angle , catalysis , engineering , sessile drop technique

Langmuir films of [C18mim][NTf2] ionic liquid exhibited, for the first time, the reversible formation of crystalline-like structures at the surface of water, compatible with the formation of multilayers. Atomistic molecular dynamics simulation results support the experimental findings, unambiguously indicating the existence of a trilayer.

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