Rational syntheses of helical π-conjugated oligopyrrins with a bipyrrole linkage: geometry control of bis-copper(ii) coordination | Zendy

Kai Zhang | Zendy; Mathew Savage | Zendy; Xin Li | Zendy; Yu Jiang | Zendy; Masatoshi Ishida | Zendy; Koki Mitsuno | Zendy; Satoru Karasawa | Zendy; Tatsuhisa Kato | Zendy; Weihua Zhu | Zendy; Sihai Yang⧫ | Zendy; Hiroyuki Furuta | Zendy; Yongshu Xie | Zendy

Open Access

Rational syntheses of helical π-conjugated oligopyrrins with a bipyrrole linkage: geometry control of bis-copper(ii) coordination

Author(s) -

Kai Zhang,

Mathew Savage,

Xin Li,

Yu Jiang,

Masatoshi Ishida,

Koki Mitsuno,

Satoru Karasawa,

Tatsuhisa Kato,

Weihua Zhu,

Sihai Yang⧫,

Hiroyuki Furuta,

Yongshu Xie

Publication year - 2016

Publication title -

chemical communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.837

H-Index - 333

eISSN - 1364-548X

pISSN - 1359-7345

DOI - 10.1039/c6cc00707d

Subject(s) - conjugated system , copper , linkage (software) , rational design , coordination geometry , chemistry , stereochemistry , crystallography , materials science , nanotechnology , molecule , organic chemistry , polymer , biochemistry , hydrogen bond , gene

A rational and effective approach for synthesizing linear π-conjugated hexa-, hepta- and octapyrrins through the regioselective oxidative coupling of monoacylated tripyrrane and bilane is described. Depending upon the numbers of pyrrolic units, the geometry and properties of bis-copper(II) complexes could be systematically modulated.

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