Pd2Au36(SR)24cluster: structure studies | Zendy

Bei Zhang | Zendy; Sameh Kaziz | Zendy; Houhua Li | Zendy; Dawid Wodka | Zendy; Sami Malola | Zendy; Оlga V. Safonova | Zendy; Maarten Nachtegaal | Zendy; Clément Mazet | Zendy; Igor Dolamic | Zendy; Jordi Llorca | Zendy; Elina Kalenius | Zendy; Latévi Max Lawson Daku | Zendy; Hannu Häkkinen | Zendy; Thomas Bürgi | Zendy; Noelia Barrabés | Zendy

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Pd₂Au₃₆(SR)₂₄cluster: structure studies

Author(s) -

Bei Zhang,

Sameh Kaziz,

Houhua Li,

Dawid Wodka,

Sami Malola,

Оlga V. Safonova,

Maarten Nachtegaal,

Clément Mazet,

Igor Dolamic,

Jordi Llorca,

Elina Kalenius,

Latévi Max Lawson Daku,

Hannu Häkkinen,

Thomas Bürgi,

Noelia Barrabés

Publication year - 2015

Publication title -

nanoscale

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 2.038

H-Index - 224

eISSN - 2040-3372

pISSN - 2040-3364

DOI - 10.1039/c5nr04324g

Subject(s) - cluster (spacecraft) , materials science , crystallography , atomic physics , physics , chemistry , computer science , programming language

The location of the Pd atoms in Pd2Au36(SC2H4Ph)24, is studied both experimentally and theoretically. X-ray photoelectron spectroscopy (XPS) indicates oxidized Pd atoms. Palladium K-edge extended X-ray absorption fine-structure (EXAFS) data clearly show Pd-S bonds, which is supported by far infrared spectroscopy and by comparing theoretical EXAFS spectra in R space and circular dichroism spectra of the staple, surface and core doped structures with experimental spectra.

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