Oxacalix[4]arene-supported di-, tetra- and undecanuclear copper(ii) clusters | Zendy

Robyn E. Fairbairn | Zendy; Ross McLellan | Zendy; Ruaraidh D. McIntosh | Zendy; María A. Palacios | Zendy; Euan K. Brechin | Zendy; Scott J. Dalgarno | Zendy

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Oxacalix[4]arene-supported di-, tetra- and undecanuclear copper(ii) clusters

Author(s) -

Robyn E. Fairbairn,

Ross McLellan,

Ruaraidh D. McIntosh,

María A. Palacios,

Euan K. Brechin,

Scott J. Dalgarno

Publication year - 2013

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/c3dt53088d

Subject(s) - tetra , cluster (spacecraft) , chemistry , copper , stereochemistry , polymer chemistry , crystallography , combinatorial chemistry , medicinal chemistry , organic chemistry , computer science , programming language

Oxacalix[4]arenes containing either one or two oxa-bridges afford di and undecanuclear Cu(II) clusters respectively upon reaction with cupric nitrate under facile conditions. Variation in reaction conditions results in formation of a tetranuclear Cu(II) cluster with mono-oxacalix[4]arene, representing a structural expansion of the dinuclear assembly.

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