New seven membered palladacycles: C–Br bond activation of 2-bromo-pyridine derivative by Pd(II) | Zendy

Juan NicasioCollazo | Zendy; Eleuterio Álvarez | Zendy; José C. AlvaradoMonzón | Zendy; Gabriel Andreu-de-Riquer | Zendy; J. Óscar C. JiménezHalla | Zendy; Luis M. De Leon Rodriguez | Zendy; Gabriel Merino | Zendy; Ubaldo Morales | Zendy; Oracio Serrano | Zendy; Jorge A. López | Zendy

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New seven membered palladacycles: C–Br bond activation of 2-bromo-pyridine derivative by Pd(II)

Author(s) -

Juan NicasioCollazo,

Eleuterio Álvarez,

José C. AlvaradoMonzón,

Gabriel Andreu-de-Riquer,

J. Óscar C. JiménezHalla,

Luis M. De Leon Rodriguez,

Gabriel Merino,

Ubaldo Morales,

Oracio Serrano,

Jorge A. López

Publication year - 2011

Publication title -

dalton transactions

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.98

H-Index - 184

eISSN - 1477-9234

pISSN - 1477-9226

DOI - 10.1039/c1dt11451d

Subject(s) - chemistry , pyridine , derivative (finance) , medicinal chemistry , coupling reaction , stereochemistry , catalysis , organic chemistry , financial economics , economics

C-Br bond activation followed by a C-C coupling reaction of the 2-bromo-pyridyl unit of [1-phenyl-2-(6-bromopyridin-2-yl)-benzoimidazole] was performed by Pd(CH(2)CMe(2)-o-C(6)H(4))(η(4)-COD). Two new seven membered palladacycles were obtained. A combined experimental and theoretical DFT study elucidates the mechanism for this reaction.

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